The fragility of liquids and colloids and its relation to the softness of the potential.
نویسنده
چکیده
A parameter that is often used to characterize the dynamics of supercooled liquids is the dynamic fragility, however it is still debated how the fragility is related to other physical properties. Recent experimental data on colloidal systems have found that fragility decreases with increasing softness of the intermolecular potential. This result is in apparent disagreement with recent molecular dynamics simulations reporting the opposite behavior. Herein, using the thermodynamical scaling exponent γ as a measure of the steepness of the potential we show how these different results can be reconciled and also agree with previous results obtained for the dynamics of supercooled liquids at high pressures.
منابع مشابه
Solvation Force in Hard Ellipsoid Molecular Liquids with Rod-Sphere and Rod- Surface Interactions
In previous work, one of us calculated the Solvation force of hard ellipsoid fluid with hard Gaussian overlap potential using hard needle wall interaction and non-linear equation proposed by Grimson- Rickyazen. In present work, using density functional theory and extended restricted orientation model, the solvation force of hard ellipsoid fluid in presence of more realistic rod- sphere and rod-...
متن کاملAnalysis of the microstructural characteristics of FSW connection of A517 (B) steel and its relation to mechanical properties and corrosion behavior
The aim of this study was to evaluate the mechanical properties and corrosion behavior of friction stir welding (FSW) connection of A517 (B) steel plate. Mechanical properties and corrosion behavior of weld zone were evaluated after reaching to optimum FSW microstructure with the lowest martensite phase. Thus, after the identifying phase microstructure by SEM and XRD analysis, mechanical proper...
متن کاملAnalysis of the microstructural characteristics of FSW connection of A517 (B) steel and its relation to mechanical properties and corrosion behavior
The aim of this study was to evaluate the mechanical properties and corrosion behavior of friction stir welding (FSW) connection of A517 (B) steel plate. Mechanical properties and corrosion behavior of weld zone were evaluated after reaching to optimum FSW microstructure with the lowest martensite phase. Thus, after the identifying phase microstructure by SEM and XRD analysis, mechanical proper...
متن کاملSeismic Fragility Assessment of Steel SMRF Structures under Various Types of Near Fault Forward Directivity Ground Motions
In this paper, the seismic collapse probability of special steel moment-resisting frame (SSMRF) structures under near fault pulse-like and far fault ordinary ground motions is evaluated through fragility analysis. For this purpose, five sample frames with 3 to 15 stories are designed and imposed to the ground motion excitations with different characteristics. Fragility curves are derived for th...
متن کاملVoltammetric Determination of Tryptophan Using a Carbon Paste Electrode Modified with Magnesium Core Shell Nanocomposite and Ionic Liquids
A novel carbon paste electrode modified with ionic liquid (n-hexyl-3-methylimidazolium hexafluoro phosphate) and magnetic core-shell manganese ferrite nanoparticles (MCSILCPE) was fabricated. The electrochemical study of the modified electrode, as well as its efficiency for electro-oxidation of tryptophan, is described. Cyclic voltammetry (CV), choronoamperometry (CHA) and square wave voltammet...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 137 20 شماره
صفحات -
تاریخ انتشار 2012